General Principles of Organic Chemistry is a Class 11 Chemistry chapter that carries about 6.3% of the Chemistry questions in NEET. Practise it with 55 questions covering 6 topics, each with an explanation.
Sample questions on General Principles of Organic Chemistry with answers
8 questions from the practice bank, spread across the chapter's topics. The full set is in the app.
Question 1: Acidity and Basicity Comparisons
Which of the following is the strongest acid?
- A CH₃COOH
- B CH₃CH₂COOH
- C ClCH₂COOH
- D FCH₂COOH
Answer: D. FCH₂COOH
Why: The strongly electron-withdrawing fluorine stabilises the carboxylate through the −I effect most effectively.
Question 2: Electronic Displacement Effects
The electromeric effect is:
- A a temporary effect that appears only in the presence of an attacking reagent
- B an effect of the solvent
- C a permanent effect in the ground state
- D a steric effect
Answer: A. a temporary effect that appears only in the presence of an attacking reagent
Why: The π electrons are transferred completely to one atom of a multiple bond.
Question 3: IUPAC Nomenclature
The IUPAC name of (CH₃)₂CHCH₂CH₂OH is:
- A 3-methylbutan-1-ol
- B isopentanol only
- C 2-methylbutan-4-ol
- D 1,1-dimethylpropan-3-ol
Answer: A. 3-methylbutan-1-ol
Why: The chain is numbered from the end nearest the –OH group.
Question 4: Reaction Intermediates
The stability of alkyl carbanions follows the order:
- A methyl > primary > secondary > tertiary
- B tertiary > secondary > primary > methyl
- C all equal
- D secondary > primary > tertiary
Answer: A. methyl > primary > secondary > tertiary
Why: Electron-donating alkyl groups destabilise a negative charge.
Question 5: Structural and Stereoisomerism
The maximum number of stereoisomers of a compound with two different chiral centres is:
- A 2
- B 8
- C 4
- D 3
Answer: C. 4
Why: 2ⁿ = 4 for n = 2.
Question 6: Types of Organic Reactions
Heterolytic fission of a covalent bond produces:
- A free radicals
- B ions (a cation and an anion)
- C neutral molecules
- D only anions
Answer: B. ions (a cation and an anion)
Why: Homolytic fission produces free radicals.
Question 7: Acidity and Basicity Comparisons
The higher acidity of phenol compared with ethanol is due to:
- A ethanol is less soluble
- B resonance stabilisation of the phenoxide ion
- C phenol has a larger molar mass
- D phenol contains no hydrogen bonds
Answer: B. resonance stabilisation of the phenoxide ion
Why: The negative charge on oxygen in phenoxide is delocalised into the ring, which an ethoxide ion cannot do.
Question 8: Electronic Displacement Effects
The number of hyperconjugation structures for the ethyl carbocation (CH₃CH₂⁺) is:
- A 3
- B 6
- C 9
- D 1
Answer: A. 3
Why: There are three α-hydrogens.