Aldehydes, Ketones and Carboxylic Acids is a Class 12 Chemistry chapter that carries about 5.2% of the Chemistry questions in NEET. Practise it with 51 questions covering 2 topics, each with an explanation.
Sample questions on Aldehydes, Ketones and Carboxylic Acids with answers
8 questions from the practice bank, spread across the chapter's topics. The full set is in the app.
Question 1: Nomenclature and Structure
A carboxylic acid is distinguished from a phenol by its reaction with:
- A bromine water
- B sodium hydroxide
- C sodium bicarbonate, which liberates CO₂
- D neutral FeCl₃
Answer: C. sodium bicarbonate, which liberates CO₂
Why: Phenols are too weakly acidic to react with bicarbonate.
Question 2: Nucleophilic Addition Reactions
A carboxylic acid reacts with an alcohol in the presence of a few drops of concentrated sulphuric acid to form:
- A an anhydride only
- B an aldehyde
- C an ester and water
- D an ether and water
Answer: C. an ester and water
Why: This esterification (Fischer esterification) is reversible, and the acid catalyst speeds up reaching equilibrium.
Question 3: Nomenclature and Structure
Formalin is:
- A a 40% solution of acetone
- B a 40% aqueous solution of formaldehyde, used as a preservative
- C pure formaldehyde gas
- D a solution of acetic acid
Answer: B. a 40% aqueous solution of formaldehyde, used as a preservative
Why: It is used to preserve biological specimens.
Question 4: Nucleophilic Addition Reactions
Propanone reacts with methylmagnesium bromide, followed by hydrolysis, to give:
- A propan-2-ol
- B 2-methylpropan-2-ol
- C 2-methylpropan-1-ol
- D butan-2-ol
Answer: B. 2-methylpropan-2-ol
Why: A ketone gives a tertiary alcohol.
Question 5: Nomenclature and Structure
The α-halogenation of carboxylic acids with Cl₂ and a trace of red phosphorus is the:
- A Cannizzaro reaction
- B Kolbe reaction
- C Etard reaction
- D Hell–Volhard–Zelinsky reaction
Answer: D. Hell–Volhard–Zelinsky reaction
Why: It gives α-chloro acids, which can be converted into amino acids.
Question 6: Nucleophilic Addition Reactions
Which acid derivative is formed on reacting a carboxylic acid with SOCl₂?
- A ester
- B acid chloride
- C amide
- D anhydride
Answer: B. acid chloride
Why: The by-products SO₂ and HCl are gases.
Question 7: Nomenclature and Structure
Stearic acid is:
- A C₁₇H₃₁COOH
- B C₁₇H₃₅COOH, a saturated fatty acid
- C C₁₇H₃₃COOH, with one double bond
- D C₁₅H₃₁COOH
Answer: B. C₁₇H₃₅COOH, a saturated fatty acid
Why: Oleic acid, C₁₇H₃₃COOH, has one C=C bond, and palmitic acid is C₁₅H₃₁COOH.
Question 8: Nucleophilic Addition Reactions
Which of the following gives a yellow precipitate of iodoform with I₂ and NaOH?
- A pentan-3-one
- B propanal
- C benzaldehyde
- D propanone
Answer: D. propanone
Why: It has a CH₃CO– group (a methyl ketone); ethanol also gives this test.