Chemical Kinetics is a Class 12 Chemistry chapter that carries about 3.2% of the Chemistry questions in NEET. Practise it with 42 questions covering 2 topics, each with an explanation.
Sample questions on Chemical Kinetics with answers
8 questions from the practice bank, spread across the chapter's topics. The full set is in the app.
Question 1: Order of Reaction and Half-Life
A first-order reaction is 75% complete in 40 minutes. Its half-life is:
- A 20 min
- B 40 min
- C 80 min
- D 10 min
Answer: A. 20 min
Why: 75% completion needs two half-lives (100 → 50 → 25% left), so t½ = 40/2 = 20 min.
Question 2: Rate of Reaction and Rate Law
If a reaction is second order in A and the concentration of A is doubled, the rate becomes:
- A four times
- B unchanged
- C eight times
- D two times
Answer: A. four times
Why: Rate ∝ [A]², so doubling [A] multiplies the rate by 2² = 4.
Question 3: Order of Reaction and Half-Life
For a zero-order reaction, the half-life is:
- A proportional to the square of the initial concentration
- B independent of the initial concentration
- C directly proportional to the initial concentration
- D inversely proportional to the initial concentration
Answer: C. directly proportional to the initial concentration
Why: t½ = [A]₀/2k for zero order, so a larger starting concentration takes longer to halve.
Question 4: Rate of Reaction and Rate Law
The rate constant of a reaction doubles when the temperature is raised from 300 K to 310 K. This approximately indicates an activation energy of:
- A 5.3 kJ/mol
- B 53 kJ/mol
- C 530 kJ/mol
- D 0.53 kJ/mol
Answer: B. 53 kJ/mol
Why: ln 2 = (Ea/R)(1/300 − 1/310), giving Ea ≈ 53.6 kJ/mol.
Question 5: Order of Reaction and Half-Life
Radioactive decay is an example of a:
- A third-order reaction
- B zero-order reaction
- C first-order reaction
- D second-order reaction
Answer: C. first-order reaction
Why: The rate is proportional to the number of nuclei present.
Question 6: Rate of Reaction and Rate Law
For the reaction 2N₂O₅ → 4NO₂ + O₂, the rate of formation of NO₂ is related to the rate of disappearance of N₂O₅ by:
- A d[NO₂]/dt = d[N₂O₅]/dt
- B d[NO₂]/dt = −2 d[N₂O₅]/dt
- C d[NO₂]/dt = −d[N₂O₅]/dt
- D d[NO₂]/dt = −½ d[N₂O₅]/dt
Answer: B. d[NO₂]/dt = −2 d[N₂O₅]/dt
Why: The stoichiometric coefficients are 4 for NO₂ and 2 for N₂O₅.
Question 7: Order of Reaction and Half-Life
A zero-order reaction is one whose rate:
- A depends on the square of reactant concentration
- B is independent of reactant concentration
- C depends linearly on reactant concentration
- D is always instantaneous
Answer: B. is independent of reactant concentration
Why: For a zero-order reaction, rate = k[A]⁰ = k, meaning the rate is constant and independent of reactant concentration.
Question 8: Rate of Reaction and Rate Law
Molecularity of a reaction:
- A is determined only by experiment
- B can be fractional
- C is always a whole number and is never zero
- D can be zero
Answer: C. is always a whole number and is never zero
Why: Molecularity is the number of species colliding in an elementary step, so it is a positive integer, while order may be fractional or zero.