p-Block Elements is a Class 12 Chemistry chapter that carries about 8.0% of the Chemistry questions in NEET. Practise it with 62 questions covering 6 topics, each with an explanation.
Sample questions on p-Block Elements with answers
8 questions from the practice bank, spread across the chapter's topics. The full set is in the app.
Question 1: Group 13: Boron Family
The correct order of acidic strength of the boron trihalides is:
- A BF3 > BCl3 > BBr3 > BI3
- B BI3 > BBr3 > BCl3 > BF3
- C BCl3 > BF3 > BI3 > BBr3
- D all four are equally acidic
Answer: B. BI3 > BBr3 > BCl3 > BF3
Why: Lewis acidity increases down the group. Back-donation from halogen lone pairs into boron's vacant p-orbital is strongest in BF3 (best 2p-2p overlap), so BF3 is the weakest acid and BI3 the strongest.
Question 2: Group 14: Carbon Family
Silicones are polymers containing the repeating unit:
- A R₂SiO
- B Si–N
- C SiC
- D SiO₂ only
Answer: A. R₂SiO
Why: They have Si–O–Si chains with organic groups on silicon, and are used as lubricants and water-repellents.
Question 3: Group 15: Nitrogen Family
Hypophosphorous acid (H₃PO₂) is:
- A tribasic
- B monobasic, because it has only one P–OH group
- C not acidic
- D dibasic
Answer: B. monobasic, because it has only one P–OH group
Why: The two P–H bonds are not ionisable.
Question 4: Group 16: Oxygen Family
Concentrated sulphuric acid chars sugar because it:
- A is a catalyst for fermentation
- B is a weak acid
- C acts as a dehydrating agent
- D acts as an oxidising agent only
Answer: C. acts as a dehydrating agent
Why: It removes the elements of water from the carbohydrate, leaving carbon.
Question 5: Group 17: Halogens
Fluorine has a lower electron gain enthalpy (less negative) than chlorine because:
- A fluorine is less electronegative
- B inter-electronic repulsion is high in the small 2p subshell of fluorine
- C chlorine has a smaller atomic radius
- D fluorine forms a stable F2 molecule
Answer: B. inter-electronic repulsion is high in the small 2p subshell of fluorine
Why: The incoming electron enters the compact 2p subshell of fluorine, where repulsion from the electrons already present offsets the energy released — so chlorine, not fluorine, has the most negative electron gain enthalpy.
Question 6: Group 18: Noble Gases
The first compound of a noble gas was prepared by Neil Bartlett. It was:
- A HeF₂
- B XeF₄
- C KrF₂
- D XePtF₆
Answer: D. XePtF₆
Why: He noticed that PtF₆ oxidises O₂ and reasoned that it should also oxidise xenon.
Question 7: Group 13: Boron Family
Aluminium reacts with aqueous sodium hydroxide to give:
- A aluminium hydroxide only
- B aluminium oxide and oxygen
- C sodium aluminate (tetrahydroxoaluminate) and hydrogen
- D no reaction
Answer: C. sodium aluminate (tetrahydroxoaluminate) and hydrogen
Why: It shows the amphoteric nature of aluminium.
Question 8: Group 14: Carbon Family
In graphite, each carbon atom is:
- A bonded to six others
- B sp hybridised in chains
- C sp³ hybridised in a tetrahedral network
- D sp² hybridised and bonded to three others in layers
Answer: D. sp² hybridised and bonded to three others in layers
Why: The delocalised π electrons between the layers account for its electrical conductivity.