D and F Block Elements is a Class 12 Chemistry chapter that carries about 3.4% of the Chemistry questions in NEET. Practise it with 44 questions covering 2 topics, each with an explanation.
Sample questions on D and F Block Elements with answers
8 questions from the practice bank, spread across the chapter's topics. The full set is in the app.
Question 1: General Properties of Transition Elements
In the 3d series, Cr²⁺ is a strong reducing agent whereas Cr³⁺ is stable because Cr³⁺ has:
- A a d⁵ configuration
- B a half-filled t₂g³ configuration, which is especially stable
- C no d electrons
- D a completely filled d subshell
Answer: B. a half-filled t₂g³ configuration, which is especially stable
Why: Cr²⁺ is oxidised to the stable Cr³⁺.
Question 2: Lanthanoid Contraction
Lanthanoid contraction refers to the:
- A steady increase in atomic/ionic radii across the lanthanoid series
- B steady decrease in atomic/ionic radii across the lanthanoid series
- C sudden increase in atomic radii midway through the series
- D disappearance of the 4f orbitals
Answer: B. steady decrease in atomic/ionic radii across the lanthanoid series
Why: Poor shielding by 4f electrons causes a steady decrease in atomic and ionic radii across the lanthanoid series.
Question 3: General Properties of Transition Elements
The spin-only magnetic moment of Ni²⁺ (3d⁸) is:
- A 4.90 BM
- B 2.83 BM
- C 3.87 BM
- D 1.73 BM
Answer: B. 2.83 BM
Why: There are two unpaired electrons: √(2 × 4).
Question 4: Lanthanoid Contraction
Compared with the lanthanoids, the actinoids show:
- A no radioactivity
- B a greater range of oxidation states, and all are radioactive
- C only the +2 state
- D only the +3 state
Answer: B. a greater range of oxidation states, and all are radioactive
Why: The 5f, 6d and 7s energies are close together.
Question 5: General Properties of Transition Elements
Transition metals and their compounds are good catalysts, and the contact process for SO₃ uses:
- A V₂O₅
- B Pt black only in the lab
- C Fe
- D Ni
Answer: A. V₂O₅
Why: Fe is used in the Haber process and Ni in hydrogenation.
Question 6: Lanthanoid Contraction
One consequence of lanthanoid contraction is that the atomic radii of the second and third transition series elements in the same group are:
- A very different from each other
- B nearly identical
- C always larger in the third series
- D unrelated
Answer: B. nearly identical
Why: Lanthanoid contraction causes the elements following the lanthanides (third transition series) to have atomic radii very similar to their second-series counterparts, despite the extra shell of electrons.
Question 7: General Properties of Transition Elements
The Ziegler–Natta catalyst, used for polymerising ethene, is:
- A PdCl₂ with CuCl₂
- B finely divided nickel
- C V₂O₅
- D TiCl₄ with Al(C₂H₅)₃
Answer: D. TiCl₄ with Al(C₂H₅)₃
Why: It gives high-density polyethylene.
Question 8: Lanthanoid Contraction
The actinoid contraction is greater than the lanthanoid contraction because:
- A 5f electrons shield the nuclear charge even less effectively than 4f electrons
- B 5f electrons shield well
- C the actinoids are lighter
- D there are fewer elements
Answer: A. 5f electrons shield the nuclear charge even less effectively than 4f electrons
Why: The 5f orbitals extend further out into space.