Electrochemistry is a Class 12 Chemistry chapter that carries about 3.2% of the Chemistry questions in NEET. Practise it with 42 questions covering 2 topics, each with an explanation.
Sample questions on Electrochemistry with answers
8 questions from the practice bank, spread across the chapter's topics. The full set is in the app.
Question 1: Electrochemical Cells and Standard Electrode Potential
The function of the salt bridge in a galvanic cell is to:
- A increase the voltage
- B conduct electrons
- C supply the electrolytes
- D maintain electrical neutrality of the two solutions by allowing ions to flow
Answer: D. maintain electrical neutrality of the two solutions by allowing ions to flow
Why: It also completes the circuit and eliminates the liquid junction potential.
Question 2: Nernst Equation and Conductance
Molar conductivity of an electrolyte solution generally increases with:
- A increasing concentration
- B decreasing concentration (dilution)
- C temperature decrease only
- D no change with concentration
Answer: B. decreasing concentration (dilution)
Why: Molar conductivity increases on dilution because ionic interactions decrease and, for weak electrolytes, the degree of dissociation increases.
Question 3: Electrochemical Cells and Standard Electrode Potential
The volume of H₂ released at STP by 1 faraday in the electrolysis of acidulated water is:
- A 44.8 L
- B 5.6 L
- C 22.4 L
- D 11.2 L
Answer: D. 11.2 L
Why: 2H⁺ + 2e⁻ → H₂, so one mole of electrons gives half a mole of H₂.
Question 4: Nernst Equation and Conductance
The emf of a cell depends on the concentration of the electrolytes, as shown by the:
- A Ohm's law
- B Nernst equation
- C Kohlrausch's law
- D Faraday's first law
Answer: B. Nernst equation
Why: E = E° − (RT/nF) ln Q.
Question 5: Electrochemical Cells and Standard Electrode Potential
In the dry (Leclanché) cell, the anode is made of:
- A copper
- B manganese dioxide
- C zinc
- D carbon
Answer: C. zinc
Why: The cathode is a graphite rod surrounded by MnO₂ and carbon.
Question 6: Nernst Equation and Conductance
The degree of dissociation of a weak electrolyte is given by:
- A α = Λm × Λ°m
- B α = Λm − Λ°m
- C α = Λ°m/Λm
- D α = Λm/Λ°m
Answer: D. α = Λm/Λ°m
Why: This is used to calculate the dissociation constant.
Question 7: Electrochemical Cells and Standard Electrode Potential
In a fuel cell using hydrogen and oxygen, the product formed is:
- A hydrogen peroxide
- B ozone
- C water
- D carbon dioxide
Answer: C. water
Why: The overall reaction is 2H₂ + O₂ → 2H₂O.
Question 8: Nernst Equation and Conductance
According to the Nernst equation, the electrode potential of a cell depends on:
- A temperature and concentration of ions only
- B the standard electrode potential and the concentration/pressure of the reacting species
- C the mass of the electrode only
- D the color of the solution
Answer: B. the standard electrode potential and the concentration/pressure of the reacting species
Why: The Nernst equation, E = E° - (RT/nF)lnQ, relates cell potential to the standard potential and the reaction quotient (concentrations/pressures), at a given temperature.