General Principles and Processes of Isolation of Elements is a Class 12 Chemistry chapter that carries about 2.0% of the Chemistry questions in NEET. Practise it with 39 questions covering 4 topics, each with an explanation.
Sample questions on General Principles and Processes of Isolation of Elements with answers
8 questions from the practice bank, spread across the chapter's topics. The full set is in the app.
Question 1: Concentration of Ores
In froth flotation, the ore particles are carried to the surface by:
- A dissolving them in cyanide
- B air bubbles, with pine oil as the froth-former
- C magnetic attraction
- D gravity separation
Answer: B. air bubbles, with pine oil as the froth-former
Why: The sulphide ore is wetted by oil, while the gangue is wetted by water.
Question 2: Extraction: Roasting, Calcination and Reduction
Calcination of zinc carbonate gives:
- A zinc hydroxide
- B zinc oxide and carbon dioxide
- C zinc and oxygen
- D zinc sulphide
Answer: B. zinc oxide and carbon dioxide
Why: ZnCO₃ → ZnO + CO₂.
Question 3: Refining of Metals
The van Arkel method for refining zirconium and titanium depends on:
- A electrolysis in molten salt
- B formation and subsequent thermal decomposition of a volatile iodide
- C distillation of the molten metal
- D oxidation of impurities by air
Answer: B. formation and subsequent thermal decomposition of a volatile iodide
Why: The crude metal is converted to a volatile iodide, which is separated from non-volatile impurities and then decomposed on a hot filament to deposit pure metal.
Question 4: Thermodynamic and Electrochemical Principles of Metallurgy
In an Ellingham diagram, a metal oxide can be reduced by carbon at a given temperature when the carbon line:
- A lies above the metal oxide line
- B lies below the metal oxide line
- C is parallel to the metal oxide line
- D has a positive slope
Answer: B. lies below the metal oxide line
Why: Reduction is feasible when the coupled reaction has a negative free-energy change, which happens where the reducing agent's line lies below that of the metal oxide.
Question 5: Concentration of Ores
Magnetic separation is used to concentrate:
- A ores of sodium
- B ores of metals found only in the free state
- C ores in which either the ore or the impurity is magnetic, such as tin stone with wolframite
- D all sulphide ores
Answer: C. ores in which either the ore or the impurity is magnetic, such as tin stone with wolframite
Why: A magnetic roller separates the magnetic particles from the non-magnetic ones.
Question 6: Extraction: Roasting, Calcination and Reduction
Copper matte consists mainly of:
- A CuCO₃ and FeCO₃
- B Cu and Fe
- C Cu₂S and FeS
- D CuO and FeO
Answer: C. Cu₂S and FeS
Why: The matte from the reverberatory furnace is charged to the Bessemer converter, where Cu₂S is converted to copper by self-reduction.
Question 7: Refining of Metals
Zone refining is used to obtain very high-purity:
- A aluminium for cooking vessels
- B semiconductors such as silicon and germanium
- C sodium
- D iron
Answer: B. semiconductors such as silicon and germanium
Why: A molten zone is passed along a rod; impurities are more soluble in the melt and are swept to one end.
Question 8: Thermodynamic and Electrochemical Principles of Metallurgy
The sulphide ores are generally converted to oxides before reduction because:
- A sulphur is a flux
- B oxides are cheaper
- C carbon cannot easily reduce sulphides (the ΔG° of formation of most sulphides is more positive than that of CS₂), and the oxides are reduced more readily
- D sulphides are insoluble
Answer: C. carbon cannot easily reduce sulphides (the ΔG° of formation of most sulphides is more positive than that of CS₂), and the oxides are reduced more readily
Why: Roasting also removes sulphur as SO₂.